© 2020 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. Enter your email address below and we will send you your username, If the address matches an existing account you will receive an email with instructions to retrieve your username, I have read and accept the Wiley Online Library Terms and Conditions of Use. EINECS 238-032-4 However, the low electric conductivity and the mismatched energy level alignment of NiOx have restricted the efficiency of NiOx based device. High performance over 20% efficiency has been achieved on NiOx base inverted PSCs. All rights reserved. Nickel tungsten oxide (NiWO4) 14177-51-6. Nickel(III) oxides are often poorly characterized and are assumed to be nonstoichiometric compounds. Finally, we will discuss current challenges of utilizing NiOx HTLs in PSCs and attempt to give probable solutions to make further development in efficient as well as stable NiOx based PSCs. It is a component of the nickel-metal hydride battery and of the nickel–iron battery. The conceptually simple structure is commonly known as the rock salt structure. Nickel oxide is a promising hole transporting material for stable perovskite solar cells. Organic materials were used as hole transporting layer previously. His present research interests are organic/inorganic semiconductor materials and their optoelectronic devices such as solar cells, LEDs, and detectors. However, cathode degradation accompanied by complex chemical and structural changes results in capacity and voltage fading in batteries. Nickel oxide (NiOx) as p-type metal oxide, owning high charge mobility and intrinsic stability, has been widely adopted in inverted PSCs. NiO adopts the NaCl structure, with octahedral Ni 2+ and O 2− sites. Nickel(III) oxide (Ni2O3) has not been verified crystallographically. Among the various cathode materials, high‐Ni cathode materials enable a high energy density. Electron probe micro‐analysis and X‐ray energy dispersive spectroscopy reveal changes in the Ni:O ratio from 1:2 to 1:1 over a large area inside the secondary particle. By continuing you agree to the use of cookies. Gary W. Morrow "Nickel(II) Peroxide" Encyclopedia of Reagents for Organic Synthesis, 2001 John Wiley & Sons. If you do not receive an email within 10 minutes, your email address may not be registered, DOI: 10.1002/smll.201701802. Dong‐Su Ko. For applications in organic chemistry, nickel oxides or peroxides are generated in situ and lack crystallographic characterization. It is a black solid that is insoluble in all solvents but attacked by base and acid. Electron energy loss spectroscopy analysis related to structural changes is performed for the entire primary particle area to visualize the oxidation state of transition‐metal ions in two dimensions. His research interests include the low dimensional semiconductor and ferroelectric perovskite and light-sensitive perovskite. It is a component of the nickel-metal hydride battery and of the nickel–iron battery. in Hubei University. He is currently a graduate student under the supervision of Prof. Haoshuang Gu in Faculty of Physics and Electronic Sciences of Hubei University. "Characterizing nickel battery materials: crystal structure of beta-(NiOOH)" Materials Research Society Symposia Proceedings (2009) 1126, p131-p136. His research interests focus on the design of high-performance and stable perovskite solar cells. Structure. Recently, more and more inorganic hole transporting materials have been deployed for further improving the device stability. The full text of this article hosted at iucr.org is unavailable due to technical difficulties. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Related materials. Doping and surficial modification are … Degradation of High‐Nickel‐Layered Oxide Cathodes from Surface to Bulk: A Comprehensive Structural, Chemical, and Electrical Analysis. Vol. We use cookies to help provide and enhance our service and tailor content and ads. Structure, properties, spectra, suppliers and links for: Nickel(II) oxide, 1313-99-1. However, the low electric conductivity and the mismatched energy level alignment of NiOx have restricted the efficiency of NiOx based device. ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. Nickel oxide for inverted structure perovskite solar cells. Copyright © 2020 Elsevier B.V. or its licensors or contributors. Casas-Cabanas, M.; Canales-Vazquez, J.; Rodriguez Carvajal, J.; Palacin, M.R. Use the link below to share a full-text version of this article with your friends and colleagues. Please check your email for instructions on resetting your password. Edited by G. Brauer, Academic Press, 1963, NY. Small 2017, 13 (45) , 1701802. Similarly it catalyzes the double oxidation of 3-butenoic acid to fumaric acid: Except where otherwise noted, data are given for materials in their. Any queries (other than missing content) should be directed to the corresponding author for the article. and you may need to create a new Wiley Online Library account. For example, "nickel peroxide" (CAS# 12035-36-8) is also closely related to or even identical with NiO(OH). Working off-campus? Fei Ma received his B.S. Nickel oxide hydroxide is the inorganic compound with the chemical formula NiO(OH). Learn more. [2] It can be prepared by the reaction of nickel(II) hydroxide with aqueous potassium hydroxide and bromine as the oxidant:[3], Nickel(III) oxides catalyze the oxidation of benzyl alcohol to benzoic acid using bleach:[4]. https://doi.org/10.1016/j.jechem.2020.04.027. Search for more papers by this author. It is a black solid that is insoluble in all solvents but attacked by base and acid. Jun‐Ho Park. The results imply that the observed monotonic capacity fade without unusual changes is due to the continuous formation of the Ni2+ phase from the surface to the bulk through chemical and structural degradation. Currently, he is a professor in Faculty of Physics and Electronic Sciences of Hubei University. Nickel(III) oxides are often poorly characterized and are assumed to be nonstoichiometric compounds. This study systematically investigates the degradation of a high‐Ni cathode by comparing the chemical, structural, and electrical changes in pristine and 500 times‐cycled cathodes.

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